Trend with pinholes and resistance?

In these trials, I used TER to look at the resistance between membranes with different amounts of pinholes. Finding a trend would produce a quicker way to scan for pinholes as opposed to checking each slot on the wafer with the microscope. The table below is my raw data.

Wafer Number of Pinholes Resistance (ohms) Average (ohms)
1 585

571

578
TEM23 1 579

580

579.5
TEM23 1 602

BROKE

602
SC024 1 660

672

666
SC075 1 641

631

636
TEM23 2 450

558

504
TEM23 2 616

611

613.5
TEM23 2 617

619

618
SC084 2 630

606

618
SC084 2 558

545

551.5
SC084 2 628

629

628.5
TEM23 3 617

610

613.5
TEM23 3 627

591

609
~50 1070

1087

1078.5
BROKEN 700

689

694.5

I could not find a trend, and I was extremely surprised when seeing a membrane with a high pinhole density (~50 pinholes) having a high resistance. I expected the resistance to be lower than the resistance in the membranes with very few pinholes.

Inconsistency in the data could be due to the construction of the sepcon. For instance, the top electrode of the EVOM needs be held each time a measurement is being taken as opposed to just being latched on when using a commercial device; the sepcon does not sit well in the device.

In conclusion, I have found no differences in resistance between 1, 2, and 3 pinholes in a membrane. Is anyone seeing something I’m not?

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