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Contributions to membrane resistance
In the soon to be submitted paper on diffusion models, we list two contributions to membrane resistance. The first is due to the steric and frictional hindrance a molecule encounters as it enters and diffuses through a pore (Renkin, Deen). The second is due to the time that it takes for the molecule to diffuse…
Water Permeability – Looking at the data
So I talked a bit with Philippe today about the water permeability data, and he suggested that I try to see if there’s a correlation between what the histogram looks like and the experimental permeability’s relation to the theory. I pulled out all the histograms and here’s what I could find. Two of the membranes…
Long Term Urea Clearance (8 hours)
SET-UP Syringe pump: 5 mL of 7.6-nmol/100µL, 5.6 µL/min pump rate. Single Channel dialyser, 10 mm long, 0.5 mm wide, 0.3 mm high in stirred beaker of DI water Fraction Collector programed to rotate every 30 min. Set up in refrigerator, 40˚C. Figure 1: Long term dialysis clearance set up in refrigerator. Syringe pump, stirred…
Updated: 25-40-25 nm OSO SEPCONS
We created a 25-40-25 OSO stack with a SEPCON pattern. RTP at 1050 C 100 C/s 60 s. The following images show a comparison between the STEM detector and the SEM detector, and then a couple more images at 100 kx and 50 kx. I calculated a porosity of ~6.5 %, and…
Bulge Testing of pnc-Si
Inspired by JP’s work with the Veeco Wyko, I attempted to fit pressure-displacement curves with the equation for thin film deformation (Vlassak and Nix 1992) for two membrane geometries: 100um x 100um and 1000um x 1000um. The relationship between displacement and pressure is: P = pressure, d = displacement, C1 and C2 are geometric coefficients,…
Energy needed for pore nucleation and growth
I first wrote about quantifying the pore formation process using kinetic theory last year. In this post, I will develop my thoughts a bit more. In the literature, researchers oftentimes present charts, like the two shown below, describing the Arrhenius behavior of silicon crystallization (Sontheimer APL 95 2009). Figures 3 and 4 show the crystal…
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At what pressure was the data in the table acquired?